In more detail
#3366cc is hsl(220, 60%, 50%). Adding 180° to the hue gives the complementary colour, here an orange (#cc9933). Lowering lightness darkens a colour without changing its hue.
HSL describes colour as hue (position on the colour wheel in degrees), saturation (intensity) and lightness, which makes tints and shades easy to create.
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#3366cc is hsl(220, 60%, 50%). Adding 180° to the hue gives the complementary colour, here an orange (#cc9933). Lowering lightness darkens a colour without changing its hue.